화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1331
발표분야 공정시스템 (Process Systems Engineering)
제목 LOHC dehydrogenation process intensification towards energy efficient, carbon-free hydrogen economy
초록 Liquid organic hydrogen carriers (LOHCs) present a potential solution for mitigation of challenges related with H2 compression and liquefaction while at the same time making use of existing fossil fuel transportation infrastructure. This work presents a process intensification strategy for a superior energy efficiency of a large scale LOHC dehydrogenation. Using a novel process concept called “temperature cascade” dehydrogenation it has been showed that a combination of LOHC chemicals utilizing a same heat source has better energy efficiency compared to a processes using a single LOHC chemical. Four LOHC candidates; Ammonia, Biphenyl / Diphenylmethane eutectic mixture, N-phenylcarbazole, and N-enthylcarbazole have been compared as a stand-alone systems and an integrated one in a rigorous process simulation using Aspen Plus. Taking into account different LOHC chemicals and varying quality of the heat source, temperature cascade dehydrogenation was shown to have the potential of doubling (on average) the energy generated per unit mass (kWh/kg) in an integrated system compared to stand-alone LOHC systems.
저자 Brigljevic Boris1, 이보름1, 강상규2, 임한권1
소속 1울산과학기술원, 2한국기계(연)
키워드 공정모델링; 공정최적화; 공정모사
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