화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 에너지변환 및 저장시스템(분자전자 부문위원회)
제목 Role of ion conducting polymer electrolytes for fuel cell systems
초록 Ion conduction in the polymer electrolytes plays an important role in the performance of fuel cell systems. Ion exchangeable groups such as sulfonic acid, carboxylic acid, phosphoric acid, etc. are attached to main polymer chains which can be fluorinated hydrocarbon or hydrocarbon. The ion exchangeable groups can be directly combined to the main chains or with a long side chain. Various types of ion conducting polymer electrolytes have totally different morphology in solvating-solvent swelled status. In general, the more hydrophilic and hydrophobic segregation between ion exchangeable groups and main chains, respectively, is distinct, the higher ionic conductivity is achieved at similar ion exchange capacity or water uptake. It is well known that the segregation is highly dependent on the chemical structure of ion conducting polymer electrolytes. In addition, the water uptake of polymer electrolytes should be kept as low as possible due to their dimensional stability.
저자 박진수1, S.S. Sekhon2, 최영우3, 김창수4
소속 1상명대, 2Department of Applied Physics, 3Guru Nanak Dev Univ., 4한국에너지기술(연)
키워드 Ion conducting; Polymer electrolyte; Fuel cell; Morphology
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