학회 |
한국고분자학회 |
학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
권호 |
35권 2호 |
발표분야 |
기능성 고분자 |
제목 |
2,6-(N,N-Diurea)-Pyridine Containing Periodic Mesoporous Organosilicas Materials |
초록 |
We have synthesized 2,6-(N,N-diurea)-pyridine containing periodic mesoporous organosilicas (PyDUPMOs) materials with intra framework urea groups with nitrogen chelating ligand (Pyridine-Diurea) via a surfactant-templated route by co-condensation of an organosilane precursor and tetraethoxy orthosilicate. The final materials were investigated in detail by means of XRD, TEM, solid state NMR, FT-IR and N2 adsorption, in order to study the effect of diurea silane group concentration on their mesoscopic order and pore structure. The material possesses hexagonal pores with a high degree of uniformity and shows long-range order as confirmed by the measurement of powder X-ray diffraction and N2 adsorption isotherms. The successful synthesis of the organosilane precursor was confirmed by liquid 1H & 13C NMR and FT-IR spectroscopic analysis. |
저자 |
산타 무티, 박성수, 수렌드란 파람바다, 하창식
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소속 |
부산대 |
키워드 |
PMO; organic-inorganic hybrid materials; pyridine-diurea; metal adsorption
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E-Mail |
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