화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 2,6-(N,N-Diurea)-Pyridine Containing Periodic Mesoporous Organosilicas Materials
초록 We have synthesized 2,6-(N,N-diurea)-pyridine containing periodic mesoporous organosilicas (PyDUPMOs) materials with intra framework urea groups with nitrogen chelating ligand (Pyridine-Diurea) via a surfactant-templated route by co-condensation of an organosilane precursor and tetraethoxy orthosilicate. The final materials were investigated in detail by means of XRD, TEM, solid state NMR, FT-IR and N2 adsorption, in order to study the effect of diurea silane group concentration on their mesoscopic order and pore structure. The material possesses hexagonal pores with a high degree of uniformity and shows long-range order as confirmed by the measurement of powder X-ray diffraction and N2 adsorption isotherms. The successful synthesis of the organosilane precursor was confirmed by liquid 1H & 13C NMR and FT-IR spectroscopic analysis.
저자 산타 무티, 박성수, 수렌드란 파람바다, 하창식
소속 부산대
키워드 PMO; organic-inorganic hybrid materials; pyridine-diurea; metal adsorption
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