| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.2037 |
| 발표분야 | 환경 |
| 제목 | Cu1+ generation in bimetallic compound of CuII[NiII(CN)4]: Effect of cathode |
| 초록 | Bimetallic complexes are robust in an enhancement of catalytic process. Laking in selective metal ion reduction and its quantification minimizes the application of bimetallic compounds in mediated electrochemical reduction (MER) process. The present investigation focuses on Cu1+ selectievely in bimetallic CuII[NiII(CN)4] by suitable electrode. The following figure shows Oxidation/reduction potential (ORP) variation during electrolysis of CuII[NiII(CN)4], where anodized Ti (TiO2) found ORP of -600 mV indicates the formation of Cu1+ only on TiO2 electrode. Additional optimization through ESR, UV-visible, and CV analyses were investigated to identify the exact metal ion reduction, especially Cu1+ formation. Key words: Selective reduction, Homogeneous mediator, Cu(I), bimetallic complex, MER. |
| 저자 | 문일식, Muthuraman Govindan |
| 소속 | 순천대 |
| 키워드 | 친환경; 고효율; 친환경 공정 |
| 원문파일 | 초록 보기 |
