| 학회 |
한국고분자학회 |
| 학술대회 |
2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터) |
| 권호 |
42권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Sythesis of Novel Carbazole Phenoxy-Based Polyurethane for High Refractive Index Material |
| 초록 |
In this study, incorporation of carbazole group and phenoxy group was used to prepare a novel polymer which has high-refractive index. Firstly, the phenoxy-based carbazole derivate (PC), which was produced by reaction between 9-(2-Oxiranylmethyl)-9H-carbazole and bisphenol AP, was combined with isophorone diisocyanate in the presence of dibutyltin dilaurate as the catalyst in subsequent step-growth polymerization, and obtained product was a prepolymer. Finally, the chain extension of this prepolymer arisen from adding bis-(2-hydroxylethyl) disulfide. The gained polyurethane (PU) was precipitated from acetone solvent with yield of 70%. This PU was characterized for molecular weight by using GPC; for chemical structure by 1H-NMR spectroscopy; for functional group by FTIR; for melting point and glass transition temperature by using differential scanning calorimetry (DSC), for decomposition by using thermal gravimetric analysis (TGA). |
| 저자 |
임권택, Trang T. K. Tu, 최원태, 서용성, 김용훈
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| 소속 |
부경대 |
| 키워드 |
High Refractive Index; Polyurethane; Carbazole; Phenoxy Group
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| E-Mail |
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