화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터)
권호 43권 1호
발표분야 분자전자 부문위원회 I
제목 Solution processed oligomeric polyurea gate insulator with hydrogen bond for low-voltage operation of flexible organic thin-film transistors
초록 We report on the fabrication of polyurea (PU) gate insulator capable of solution process for low-voltage operation and high performance organic thin-film transistors (OTFTs). We synthesized solution-processable polyurea by precisely controlling hydrogen bonding through molecular design and molecular weight. A 60 nm-thick PU thin film exhibited high dielectric constant of 5.82 and excellent electrical insulating properties. To investigate the potential of the PU thin film as a gate insulator, we fabricated flexible dinaphtho[2,3-b:20,30-f]thieno[3,2-b]thiophene (DNTT) OTFTs. The DNTT TFTs with the 60 nm-thick PU gate insulator showed excellent TFT performance with a field-effect mobility of 1.390 cm2/Vs and an on/off ratio of 5.84x105 at a low operation voltage below 3V. In addition, the mobility of DNTT TFTs significantly improved with simple metal-oxide assisted surface treatment on PU gate insulator. These flexible TFT devices were successfully operated after 1000-times bending test.
저자 유성미1, 김윤호1, 김동균1, 원종찬1, 장광석2, 하태욱1
소속 1한국화학(연), 2UST
키워드 gate insulator; OTFT; polyurea
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