| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 |
17권 2호 |
| 발표분야 |
에너지 저장 및 Solar Fuels |
| 제목 |
태양광 활용 물분해 수소제조를 위한 포피린-이산화티탄 가시광광촉매 개발 (Development of Tetra(4-carboxyphenyl) porphyrin Sensitized TiO2 for Phocatalytic Water Splitting using Visible Light) |
| 초록 |
Porphyrins are well known photosensitizer because of their strong absorption in visible region. Various porphyrins having different funtional group such as tetra-phenyl-porphyrin (TPP), tetra-4-hydroxyphenyl-porphyin (THPP), and tetra-4-carboxyphenyl-porphyin (TCPP) have been synthesized and anchored on TiO2 surface. Their anchoring properties and activities of porphyrin-TiO2 complexes for photocatalytic oxidation of organic compounds such as methyl orange (MO) and the production of molecular hydrogen via water splitting has been investigated. It was observed that TCPP showed the strong adsorption on TiO2 and the best phorocatalytic activity. In addition, metalloporphyrins such as Cu and Sn has been also synthesized and used as photosensitizer and catalyst for photocatalytic water splitting. |
| 저자 |
최지나, 유지선, 황지나, 권순일, 김범식
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| 소속 |
한국화학(연) |
| 키워드 |
물분해; 수소제조; 이산화티탄; 포피린; 가시광촉매
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| E-Mail |
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