| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Synthesis and Characterization of an Ionic Polyacetylene Derivative via the Non-catalyst Polymerization of Ethynylpyridines |
| 초록 |
A new class of ionic polyacetylenes has been synthesized via the non-catalyst polymerization of ethynylpyridines by the substituted functional halides. Here, we prepared a new ionic polyacetylene with N-substituted pyridinium substituents via the uncatalyzed polymerization of 2-ethynylpyridine by the cyclic compound such as 1,3-propanesultone. The polymers were completely soluble in such organic solvents as DMF, NMP, and DMSO including water. The kinetics of the redox process of polymer were found to be controlled by the reactant diffusion process from the experiment of the current oxidation density of polymer versus the scan rate. |
| 저자 |
임권택1, 심상연2, 박종욱3, 진성호4, 제갈영순5
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| 소속 |
1부경대, 2강릉원주대, 3가톨릭대, 4부산대, 5경일대 |
| 키워드 |
non-catalyst; ethynylpyridine; ring-opening; cyclic compound; characterization; photoluminescence
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| E-Mail |
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