| 학회 |
한국화학공학회 |
| 학술대회 |
2018년 가을 (10/24 ~ 10/26, 대구 EXCO) |
| 권호 |
24권 2호, p.1607 |
| 발표분야 |
에너지 환경(Energy and Environment) |
| 제목 |
Applying new polymers containing phosphate as the electrode binder for high temperature PEMFC |
| 초록 |
The high-temperature polymer electrolyte membrane fuel cell (HT-PEMFC) is operated between 120℃ and 180℃, so it can’t use the Nafion® as a binder for the electrodes because proton conductivity of the Nafion® is very low without water. Therefore, the HT-PEMFC used phosphoric acid (PA) to conduct protons from the anode to the cathode and binder, such as polyvinylidene fluoride (PVDF), to maintain the electrode structure. In this study, the polymers having the phosphate group as a functional group, that has a proton conductivity under the low humidity, is attempted to use as a new binder for the HT-PEMFC. Hydrocarbon-based polymers were used because they are stable at high temperatures. The polymer containing phosphate in the side chain was synthesized by Arbuzoy reaction. There are three types of polymers depending on the length of side chain. The binder had the longer the side chain, the higher the performance. The NMR and FT-IR showed the changes of interaction between a binder and organic additive at high temperature. The optimization of performance will be discussed. |
| 저자 |
김도형1, 민청민2, 이은애1, 이재석2, 박찬호1
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| 소속 |
1광주과학기술원 융합기술원 융합기술학제학부 에너지프로그램, 2광주과학기술원 신소재공학부 |
| 키워드 |
에너지 환경 |
| E-Mail |
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| 원문파일 |
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