화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아)
권호 17권 2호, p.1181
발표분야 고분자
제목 Preparation and characterization of polystyrene/silica composite nano-spheres
초록 Organic/inorganic composite materials have been extensively studied for a long time to combine the advantages of individual materials. Especially the preparation of mono-dispersed latex spheres has received considerable academic and industrial attention due to their wide applications. Average particle sizes and narrow size distributions are important factors for most applications. In this work, polystyrene latex spheres (PLS) containing silanol groups are firstly synthesized by emulsion polymerization using methyltrimethoxysilane (MPS) as a functional monomer. Then, a silica layer is formed on the copolymer particle surface by the reaction with tetraethylorthosilicate (TEOS) in aqueous solution. The morphology of the composite latex spheres are studied using a scanning electron microscope (SEM) and the particle size distributions are obtained by a particle size analyzer. The particle size of the composite latex spheres is controlled by changing reaction temperature, solution pH, the concentrations of an initiator, potassium persulfate (KPS), and a stabilizer, sodium dodecyl sulfate (SDS) and the agitation speed.
저자 김옥희1, 황민진1, 류동완1, 이준석2, 문 희1
소속 1전남대, 2(주) 동양화학
키워드 polystryene latex sphere (PLS); polystyrene/silica composite
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