학회 |
한국화학공학회 |
학술대회 |
2012년 봄 (04/25 ~ 04/27, 제주 ICC) |
권호 |
18권 1호, p.60 |
발표분야 |
고분자 |
제목 |
Synthesis and evaluation of polystyrene-silica composite nanospheres under various conditions |
초록 |
Monodispersed polystyrene-silica composite nanospheres were synthesized by a two-step process in order to improve the thermal stability as artificial dusts. The poly(styrene-co-MPS) copolymer spheres containing silanol groups were firstly prepared as seed spheres by emulsion polymerization using 3-(trimethoxysilyl)propyl methacrylate (MPS) as a co-monomer, potassium persulfate (KPS) as an initiator, and sodium dodecyl sulfate (SDS) as a stabilizer. Later silica layers were grown on the seed copolymer spheres by a sol-gel reaction with tetraethylorthosilicate (TEOS) in aqueous solution at room temperature. It was experimentally proven that silica layers greatly enhance the thermal stability of nanospheres. |
저자 |
김옥희1, 황민진1, 류동완1, 성동찬2, 문 희1
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소속 |
1전남대, 2동양화학 |
키워드 |
monodispersed; polystyrene-silica composite; nanospheres
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E-Mail |
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