| 학회 |
한국화학공학회 |
| 학술대회 |
2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 |
25권 1호, p.715 |
| 발표분야 |
재료(Materials) |
| 제목 |
A High-Capacity, Reversible Liquid Organic Hydrogen Carrier: Production of Hydrogen and an Application to a Fuel Cell |
| 초록 |
Hydrogen storage in the form of liquid chemical is very essential because the supply and demand of hydrogen can happen at different site. In this study, the application of a hydrogen storage material which is a eutectic mixture of biphenyl (35 wt%) and diphenylmethane (65 wt%) has been demonstrated. The proposed material is able to reversibly store and produce molecular hydrogen with 6.9 wt% and 60 g-H2 L-1 of gravimetric and volumetric hydrogen storage capacities. Experimentally, conversion of dehydrogenation was higher than 99%, and hydrogen produced by dehydrogenation reaction had a purity of over 99.9%, with negligible side reactions. Further, this was confirmed via NMR spectroscopy. After a total of 9 cyclic tests of hydrogenation and dehydrogenation, there was a loss of less than 1%. Finally, a dehydrogenation system is designed and operated in conjunction with a PEM fuel cell that can generate higher than 0.5 kW of electrical power continuously, verifying its capability as a promising liquid organic hydrogen carrier. |
| 저자 |
장문정1, 조영석1, 이원종1, 신병수2, 손현태1, 정향수1, 장성철1, 김영천1, 곽상규3, 강정원2, 윤창원1
|
| 소속 |
1한국과학기술(연), 2고려대, 3울산과학기술원 |
| 키워드 |
재료 |
| E-Mail |
|
| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
