초록 |
Microporous materials are widely used in gas storage, catalysis, and separation because of their high surface areas and small pore sizes. In this study, we prepared graphene-incoporated microporous polymers through Sonogashira cross-coupling reactions of tetrakis(4-ethynylphenyl)adamantane, triethynyl benzene, dibromoterephthalic acid, and acetylene-functionalized graphene. Graphene has a single-atom thickness and a high surface area. Its incorporation into microporous polymers was expected to produce microporous hybrid materials with high gas uptakes. The pore structures and gas uptake behaviors of the microporous hybrid materials were investigated. |