| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Novel sulfonated poly(arylene ether sulfone) membranes with two different bisphenol moietiesfor a fuel cell application |
| 초록 |
The proton transport properties of the ion exchange membranes are strongly associated with the morphology in microstructure. Most changes in morphology are mainly cause to bring out the occurrence of the partial phase separation between hydrophilic-hydrophobic segments of the membrane. It could be controlled by several ways such as a block-copolymerization, an introduction of co-monomers, a polymer-blend, and so on. In this study, novel proton-exchange membranes based on partially sulfonated poly(arylene ether sulfone)s (SPAESs) with two-different bisphenol moieties of 4,4’-hexafluoroisopropylidenediphenol (6F-BPA) and 9,9’-bis(hydroxy phenyl)fluorene (HPF) were fabricated by a direct polymerization and a subsequent solution casting technique. Resulting copolymers were characterized by various analytic methods, and their membrane properties were examined thoroughly for fuel cell applications. |
| 저자 |
최준규1, 고하나1, 최종호1, 김형중2, 홍영택1
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| 소속 |
1한국화학(연), 2공주대 |
| 키워드 |
sulfonated polymer; proton-exchange membranes; phase separation; co-monomers; fuel cell
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| E-Mail |
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