| 학회 | 한국공업화학회 |
| 학술대회 | 2014년 가을 (11/12 ~ 11/14, 엑스코(대구)) |
| 권호 | 18권 2호 |
| 발표분야 | 고분자-포스터 |
| 제목 | Synthesis and Photoinitiated Radical Polymerization of Silicone containing Acrylamide |
| 초록 | The synthesis of N-triisopropylsilyloxyethylacrylamide(NSA) was carried out in high yields by the condensation reaction of the N-hydroxyethylacrylamide with chlorotriisopropylsilane. This novel silicone containing acrylamide undergo rapid photoinitiated radical polymerization using Igacure651 as a photoinitiator. Photoinitiated radical polymerization of silicone containing monomer was undertaken using photoinitiator, Igacure651 at a concentration 0.5~1 mol% to the monomer. The rate of polymerization and conversions to polymer are increased as the increase in concentration of the photoinitiator. A series of water-swollen hydrogels were prepared from 2-hydroxyethyl methacrylate(HEMA), ethylene glycol dimethacrylate and NSA. AIBN was used as an initiator for polymerization. Analyzing the water contents and contact angles of the hydrogels, we found the contents of silicone containing monomer increased, water content decreased and contact angles increased. |
| 저자 | 김기상1, 심상연1, 제갈영순2 |
| 소속 | 1강릉원주대, 2경일대 |
| 키워드 | containing Acrylamide; Photoinitiat |
