| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
| 권호 |
14권 1호, p.87 |
| 발표분야 |
고분자 |
| 제목 |
Cycloolefin Polymer (COP) Synthesis with Ring Opening Metathesis Polymerization (ROMP) |
| 초록 |
A new engineering plastic, cycloolefin polymer (COP) has excellent optical properties as well as good mechanical, flow properties. The major potential applications of COP are substrates for next – generation high density DVDs, flat –panel displays and plastic optical fibers. In this study, ring-opening metathesis polymerization (ROMP) of norbornene (NB) and tetracyclododecene (TCD) monomer was carried out using various catalysts. The catalysts includes a Zigler – type catalyst of titalnium tetrahalide, metathesis – type catalyst of hexacholoride tungsten, and 1st generation Grubbs catalysts. Polymerization yield above 90 % can be obtained without gelation by controlling polymerization conditions. |
| 저자 |
김완주1, 김재덕1, 김재훈1, 이현주1, 오성근2
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| 소속 |
1한국과학기술(연), 2한양대 |
| 키워드 |
cycloolefin polymer(COP); ring-opening metathesis polymerization (ROMP); norbornene (NB); tetracyclododecene (TCD);
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| E-Mail |
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| 원문파일 |
초록 보기 |
