화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 기능성 고분자 (포스터발표만 진행)
제목 Elucidation for the silver-mediated fluorescence enhancement of DNA-templated AgNCs: a selective fluorogenic probe for the detection of nanomolar silver ions
초록 Silver ion mediated fluorescence enhancement on DNA-templated silver nanoclusters (DNA-AgNCs) is investigated as new, simple, sensitive and rapid type of silver ion detection probe. The DNA-AgNCs probe is prepared by chemical reduction method using air-saturated distilled water solution. Through analyzing the DNA-AgNCs probe using fluorescence spectroscopy and mass spectrometry, silver ion plays a role as a bridge for two DNA-AgNCs strands which emits strong green fluorescence as 43.9 % of quantum yield relative to Rhodamine 6G. Also utilizing the fluorescence enhancement of DNA-AgNCs by silver ions addition, we suggest a quantitative silver ion detection method which has low detection limit as 10 nM.
저자 이지현, 김원종
소속 포항공과대
키워드 DNA templated silver nanoclusters; silver ion detection
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