화학공학소재연구정보센터
학회 한국재료학회
학술대회 2013년 봄 (05/23 ~ 05/24, 여수 엠블호텔(THE MVL))
권호 19권 1호
발표분야 제24회 신소재 심포지엄-나노분산 및 복합화기술
제목 Homogeneous dispersion of graphene nanosheets in water by hybridization with conjugated polymer
초록 Graphene nanosheets hybridized with conjugated polymer (PDA, polydiacetylene) were prepared for homogeneous dispersion and further functionality of graphene in water. Diacetylenic monomers were self-assembled and photo-polymerized on reduced graphene oxide (RGO) for non-covalent functionalization. The PDA/RGO nanohybrids demonstrated the formation of conjugated polymer on graphene surface for fluorescence and electrochemical detection. The optical and structural properties of PDA/RGO nanohybrids, characterized by UV-Vis, FT-IR, Raman, and photoluminescence spectrometers, supported that PDA and RGO are connected by physical interactions and not by chemical bonds. Further-functionalization of PDA/RGO with biotin was verified in microfluidic biochip via biotin-straptavidin interaction. The electrochemical experiments showed the potential of functionalized RGO for use as an electrochemical biosensor, especially with the detection of an analyte at low concentration.
저자 윤지선1, 김도현2, 정영훈1, 남중희1, 조정호1, 백종후1
소속 1한국세라믹기술원, 2KAIST
키워드 graphene; dispersion in water; polyme/graphene nanohybrids
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