학회 | 한국화학공학회 |
학술대회 | 2002년 봄 (04/26 ~ 04/27, 강원대학교) |
권호 | 8권 1호, p.1777 |
발표분야 | 고분자 |
제목 | 반응상용화제의 미시적 구조가 비상용성 고분자 계면에 미치는 효과에 관한 몬테카를로 기법을 이용한 연구 |
초록 | Block copolymers containing dissimilar types of monomers can be used to tail the properties of immiscible polymer interfaces. One of the most important methods for introducing copolymers to the interface is reactive blending, i.e. the in-situ formation of block copolymers at the interface. Compared to simple admixing of copolymers, chemical reactions generate stronger interfaces and more effectively enhance mechanical blending of thermodynamically incompatible polymer species. A large body of literature has so far been focused on the effect of reactive polymers on morphology and adhesion. Because the structure of the reactive polymer and functionality of reactive polymers are crucial to understand the interfacial properties, we focused on the effects of functionality and molecular weight of reactive polymers on the reaction kinetics and the conformation of copolymers formed at the interface due to reaction. |
저자 | 양유성, 차국헌 |
소속 | 서울대 |
키워드 | mono-endfunctional polymer; di-endfunctional polymer; reaction kinetics; Monte Carlo Simulation |
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VOD | VOD 보기 |
원문파일 | 초록 보기 |