| 학회 |
한국공업화학회 |
| 학술대회 |
2007년 가을 (11/02 ~ 11/03, 한경대학교) |
| 권호 |
11권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Polyolefin Catalytic Activity of Aryloxide Titanium Complexes by Electro Push-pull Substituents |
| 초록 |
The attachment of electron-donating or electron-withdrawing aryl groups to the 4-position of the 2-phenylphenolate ligand via Suzuki coupling were developed. Corresponding half-titanocene complexes were obtained by reacting the electron-donating or electron-withdrawing aryl group ligands with Cp*TiCl3. CV spectra of complexes were shown clearly by a decrease of reduction potential with increase of electric donating power of aryl substituents. A successful tuning in the catalytic activity of polymerization of ethylene was achieved: the catalytic activity was found to correlate with the Hammett constant of the respective substituents, providing a powerful strategy for prediction of the catalytic activity of new polyolefin catalyst. |
| 저자 |
김태진, 김성관, 고재중, 강상욱
|
| 소속 |
고려대 |
| 키워드 |
metallocene; polyolefin; catalyst
|
| E-Mail |
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