학회 |
한국공업화학회 |
학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
권호 |
10권 2호 |
발표분야 |
고분자 |
제목 |
Synthesis and characteristics of Fluorinated Polyurethane from Novel telechelic fluoropolyol based on VDF/HFP copolymer |
초록 |
The well-defined α,ω-diiodo-poly(VDF-co-HFP) was polymerized by Iodine Transfer Polymerization. These α,ω-diiodo-poly(VDF-co-HFP) were converted to α,ω-bis(hydroxyethyl)-poly(VDF-co-HFP) after the addition of one ethylene unit, followed by the hydrolysis using water and a phase-transfer reagents in polar aprotic solvent. The structure and functionality of these dihydroxy fluoro polymers were characterized by NMR. As these fluorinated polyol with the molecular weight below 4,000g/mol were used as telechelic fluorinated prepolymer for the sythesis of fluorinated polyurethane with low surface energy, good physical properties. |
저자 |
이정환1, 송종권1, 강철한1, 유호준1, 김나리1, 원종웅2, 이범재1
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소속 |
1충남대, 2한화(연) |
키워드 |
Fluoropolymer; Fluorinated Polyol; Poly(vinylidene fluoride(VDF)-co-hexafluoropropylene(HFP)]; Fluorinated Polyurethane
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E-Mail |
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