| 학회 |
한국화학공학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
10권 2호, p.2250 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
Synthesis of Nano-Structured TiO2 using Ionic Liquids as an Effective Template |
| 초록 |
Nano-structured TiO2 particle has been prepared with water immiscible room temperature ionic liquid (WIRTIL) as an effective template by sol-gel method and compared with TiO2 particle prepared by conventional method. Ionic liquids (ILs) are an exceptional type of solvent possessing no vapor pressure and tunable solvent properties. A possible mechanism for the formation of this nanostructured TiO2 particle is an effective aggregation of the TiO2 particle with a self-assembled IL. Considering the special structure of IL, water molecules preferentially interact with anion on the IL strongly through hydrogen bond whereas the imidazolium rings pile up and stack by π-π interaction. It was found that the nanostructured TiO2 particle using WIRTIL had good structural characteristics including high surface area, anatase phase, controlled porosity and tailor-designed pore size distribution for several applications. |
| 저자 |
유계상, 문동주, 최은형, 백종운, 김용식, 안병성
|
| 소속 |
한국과학기술(연) |
| 키워드 |
Nanostructure; TiO2; Ionic liquid
|
| E-Mail |
|
| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
