화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔)
권호 12권 1호, p.232
발표분야 분리기술
제목 Adsorption Energy Distribution Functions for Single-Walled Carbon Nanotubes (SWCNT)
초록 SWCNT was characterized by nitrogen adsorption/desorption isotherm, SEM, TEM, and Raman Spectroscopy. The equilibrium data of VOCs (Benzene, Toluene and m-Xylene) on SWCNT were measured at three different temperatures (303.15, 313.15 and 323.15 K) with pressures up to saturated pressure. The nitrogen and VOC isotherms exhibit typeⅡ and type I, respectively. The isotherm data were well fitted by Toth and UNILAN models. The isosteric heat of adsorption was calculated by Clausius-Clayperon equation. In addition, adsorption energy distribution functions were evaluated by generalized nonlinear regularization method. We found that SWCNT have energetically and structurally heterogeneous surfaces.
저자 강현철1, 심왕근1, 김 찬1, 이재욱2, 서숭혁3, 문 희1
소속 1전남대, 2서남대, 3계명대
키워드 adsorption; SWCNT
E-Mail
원문파일 초록 보기