| 학회 |
한국고분자학회 |
| 학술대회 |
2002년 가을 (10/11 ~ 10/12, 군산대학교) |
| 권호 |
27권 2호, p.233 |
| 발표분야 |
고분자 합성 |
| 제목 |
Ionic Conjugated Polymers from 2-Ethynylpyridine and Alkyl halides |
| 초록 |
Poly(2-ethynylpyridinum bromide) having various alkyl side chains was prepared by the spontaneous polymerization of 2-ethynylpyridine and the corresponding alkyl halides under mild reaction conditions without any initiator and catalysts. The polymerization proceeded well to give the resulting ionic conjugated polymers with alkyl side chains in relatively high yields. Various spectral data for the polymer structure indicated that the conjugated polymer system having N-alkylpyridinum substituent was formed. This ionic polymer was mostly soluble in water, methanol, DMF, DMSO, and N,N-dimethylacetamide, and well processible into thin homogeneous film. The photoluminescence and thermal properties of the polymers were also studied. |
| 저자 |
이상섭1, 배장순2, 고광락*3, 김성훈**4, 박종욱***5, 진성호****6, 제갈영순*****
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| 소속 |
1단국대, 2*경북대, 3**경북대, 4***충주대, 5**** 부산대, 6*****경일대 |
| 키워드 |
2-ethynylpyridine; polyacetylene; conjugated polymer
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| E-Mail |
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