| 학회 |
한국고분자학회 |
| 학술대회 |
2002년 가을 (10/11 ~ 10/12, 군산대학교) |
| 권호 |
27권 2호, p.202 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Synthesis of Poly(9,9’-spirobifluorene-2,7-vinylene)-Derivatives by Gilch Polymerization |
| 초록 |
Fluorene-based light-emitting polymers tend to form aggregates or excimers during the device operation due to the rigid and planar biphenyl units. In order to solve this problem, we introduced a more bulkier substitutent, spirofluorene in carbon 9 position of fluorene. Poly(9,9’-spirobifluorene-2,7-vinylene) was synthesized by dehydrohalogenation method. The resulting polymer was completely soluble in toluene and partially soluble in most of organic solvents. The thermal and optical properties of poly(9,9’-spirobifluorene-2,7-vinylene) were investigated with poly(9,9’-dioctylfluorene-2,7-vinylene) for comparison. Details of EL characteristics of this polymer will be discussed. |
| 저자 |
박혜진1, 진성호2, 김진영*3, 이광희*4, 제갈영순**, 조현남***
|
| 소속 |
1부산대, 2*부산대, 3**경일대, 4***한국과학기술(연) |
| 키워드 |
light-emitting diode; poly(spirofluorenevinylene); Gilch polymerization
|
| E-Mail |
|
