| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
블록공중합체를 이용한 신기능 나노물질 개발 및 분석 |
| 제목 |
Pressure effect on weakly interacting block copolymer investigated by FTIR spectroscopy |
| 초록 |
The transition temperatures of deuterated polystyrene-block-poly(n-pentyl methacrylate) copolymers with the closed-loop phase behavior are known to be very sensitive to hydrostatic pressure. To clarify the origin of the pressure dependence on transition temperature of a weakly interacting block copolymer, pressure-dependent Fourier transform infrared (FTIR) spectra was obtained at various temperatures. It was found that the functional groups belonging to PnPMA block compared with PS block are much more sensitive to pressure. Interestingly, the functional groups sensitive to pressure are different from those sensitive to temperature. Acknowledgement: This work was supported by Creative Research Initiative Program supported by KOSEF |
| 저자 |
김혜정1, 김진곤1, 정영미2, 김승빈1
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| 소속 |
1포항공과대, 2강원대 |
| 키워드 |
block copolymer; FTIR spectroscopy; pressure
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| E-Mail |
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