| 학회 | 한국공업화학회 |
| 학술대회 | 2012년 가을 (10/31 ~ 11/02, 대전컨벤션센터) |
| 권호 | 16권 2호 |
| 발표분야 | 포스터-촉매 |
| 제목 | Effect of Si/Al ratio on the selective epoxidation of di-cyclopentadien using Ti containing zeolite |
| 초록 | Catalytic propertyes of Ti-HY for the epoxidation of di-cyclopentadiene(DCPD) was investigated and made a comparison with those of TS-1. Higher efficiency of Ti-HY was observed in the epoxidation of DCPD. Ti-HY showed the best yield in the epoxidation of DCPD. The study was also investigated in terms of Ti content in the catalysts, H2O2/substrate ratio, temperature, reaction time, Si/Al ratio, and solvent, significantly influenced the reaction activity and selectivity. The Si/Al ratio of zeolite on the reaction conditions significantly influenced the catalytic activity and selectivity. Also titanium containing in zeolite was confirmed by FT-IR and UV-Visible analysis. |
| 저자 | 최경민1, 신은진1, 고문규1, 윤병태2, 김영운2, 정근우2, 김성보2 |
| 소속 | 1건양대, 2한국화학(연) |
| 키워드 | DCPD; Epoxidation; Ti-Zeolite |
