| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.2040 |
| 발표분야 | 환경 |
| 제목 | Mediated electrochemical reduction study of [Ni(II)(CN)4]2- complex in the 1-butyl-3-methylimidazolium hexafluorophosphate RTIL |
| 초록 | Redox behavior of transition complex like Ni(Salen), Co(Salen), Ni(byp) have been reported earlier but cyano complex yet to be revealed before. Therefore the main objective of this work focused on the study of electrochemical redox behavior of Ni2+ to Ni+ through the [Ni(II)(CN)4]2- complex in bmimpf6 RTIL. The cyclic Voltammogram of 5 mM [Ni(II)(CN)4]2- complex at 50 mV s-1 shows an irreversible redox behavior at -1.4V (red color), which is more positive than the without Ni-mediator tells mediator effect. Key words: RTIL, bmim PF6 IL, [Ni(CN)4]2- complex, redox behavior. |
| 저자 | Kannan Karunakaran, 문일식 |
| 소속 | 순천대 |
| 키워드 | 친환경; 고효율; 친환경 공정 |
| 원문파일 | 초록 보기 |
