| 초록 |
Phthalocyanine (Pc) finds a variety of useful applications, mainly due to its outstanding stability, architectural flexibility, and diverse coordination properties. Generally speaking, Pc, containing an extended electron-rich aromatic macrocycle, exhibits superior spectroscopic characteristics and fascinating electrical/electrochemical properties. Herein we plan to cover the synthesis and electrochemical applications of Pc macromolecules, with a focus on the synthesis of symmetrical and unsymmetrical Pc derivatives and their inclusion into macromolecular architectures. We have intuitively manipulated the synthetic routes to prepare peripheral-substituted Pc derivatives. By doing this, it has been reasonably intended to increase the effective conjugation length, provide preferential reaction sites, and thus enhance the chemical and electrochemical activity of Pc macromolecules. In addition, Pc/carbon hybrid materials and donor-acceptor type conjugated polymers will be detailed as well. |
