| 초록 |
1,2,3-Triazole-embedded polyacrylates were synthesized using Cu1-catalyzed 1,3-dipolar cycloaddition of azide and alkynes. Monomers with azido or nitro groups were polymerizaed via controlled radical polymerization. Novel monomers, 3-azidopropyl acrylate(AzPA) and 2,2-dinitropropyl acrylate were polymerized via RAFT with good control of the polymer molecular weight distribution. Azido containing polymer was coupled with PEG-based acetylene or acetylene including functional group via a highly efficient "click" reaction. |
