| 학회 |
한국공업화학회 |
| 학술대회 |
2011년 가을 (11/02 ~ 11/04, 경원대학교) |
| 권호 |
15권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis of High Energetic Polyacrylate-PEO copolymer |
| 초록 |
Poly(3-azidopropyl acrylate) and poly(2,2'-dinitropropyl acrylate) as high Energetic copolymers were polymerized via controlled radical polymerization, ATRP or RAFT. PolyAzPA was achieved at room temperature because the azido group is unstable under high temperature condition. These azido containing polymer was coupled with dinitro acetylenes or PEG acetylenes via a highly efficient "click" reaction andhigh energetic polymer containing thiol-end group synthesized by RAFT process was coupled with PEG alkenes via thiol-ene reaction to be utilized as a promising energetic binder. |
| 저자 |
이혜림, 이범재, 박종혁, 배인주, 최인환
|
| 소속 |
충남대 |
| 키워드 |
CRP; RAFT; nitro; azido; click
|
| E-Mail |
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