화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 분자전자 부문위원회
제목 Organic Sensitizers containing Ullazine chromophore for Dye-Sensitized Solar Cells
초록 Many metal-free organic dyes have been used in DSSCs such as coumarin, merocyamine, indoline the molecular structure of the electron donor and the acceptor bridged by the conjugated chain (D-π-A). More and more efforts have been dedicated to development of metal-free organic dyes which exhibit not only higher molar extinction coefficients, but also simple preparation and purification procedures at lower cost. In this article, we have developed novel organic dyes in which the ullazine core was used as the π-bridge and various donor groups were added for the application of DSSCs. An aromatic, 14π-electron annulene resonance structure consisting of a centralized electron density from the inplane nitrogen provides the potential donating strength as well as electron stabilizing properties of this nitrogen-containing heterocycle. The photovoltaic performance of DSSC composed of organic chromophores were measured and evaluated by comparison with that of pristine ruthenium dye.
저자 Le Quoc Bao, Nguyen Thi Hai, 이치환, 김동우, 김재홍
소속 영남대
키워드 chromophore; Dye-Sensitized Solar Cells
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