| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 |
21권 2호 |
| 발표분야 |
(석유화학윤활유) 미세먼지 저감 수단으로서 열분해 바이오오일의 개발과 적용 |
| 제목 |
Pyrolysis kinetics and fast pyrolysis of pre-treated algal Saccharina Japonica |
| 초록 |
The effect of water-washed Saccharina japonica (S. japonica) samples on pyrolysis product distribution was studied at 360, 370 and 380 ℃ with various residence times from 1.0 to 3.0 min. The kinetic rate constants of pyrolysis for untreated and water-washed S. japonica samples were determined using nonlinear least-squares regression of experimental data assuming first-order kinetics. As high mineral contents in S. japonica cause ash fouling or agglomeration of char and bed material in fluidized-bed reactor, S. japonica was water-washed as pretreatment to remove minerals and sticky materials. The yields of bio-oil were 25.57-31.27 wt% under the investigated pyrolysis conditions (temperature: 350-450 ℃; fluidization velocity: 2.0×Umf-4.5×Umf). The highest bio-oil yield (31.27 wt%) from water-washed S. japonica was obtained at 375 ℃ and 4.0 Umf, and the HHVs of the organic and aqueous phases in the bio-oil were 31.47 and 5.41 MJ/kg, respectively. |
| 저자 |
김승수1, 최재형2, 김진수3, 우희철2
|
| 소속 |
1강원대, 2부경대, 3경희대 |
| 키워드 |
Brown algae; Water-washed Saccharina japonica; Lump kinetic model; Pyrolysis; Bio-oil
|
| E-Mail |
|
