화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전))
권호 33권 1호
발표분야 고분자 합성
제목 Grafting of Polyaniline onto the Surface of Amine-Functionalized Multi-Walled Carbon Nanotubes
초록 Less destructive chemical modification of various carbon nanotubes (CNTs) via electrophilic substitution reaction in a mild polyphosphoric acid (PPA)/phosphorous pentoxide (P2O5) medium has been developed. Even though functionalized MWNTs (F-MWNT) are almost no or minimum damaged, introducing organics onto the sidewall of MWNT could still reduce electric and thermal conductivities on its surface. Thus, to minimize the surface damages of MWNTs and to maintain the conductivities of resultant nanocomposites, we would like to introduce organics containing reactive functional groups via electrophilic substitution reaction to afford F-MWNT. Electrically conductive polyaniline (PANi) was grafted to the surface of F-MWNT via in-situ polymerization. As a result, the conductivities of resultant nanocomposite would be less sacrificed and the solubility of nanocomposite could be further enhanced due to grafting of PANi.
저자 전인엽1, Loon-Seng Tan2, 백종범1
소속 1충북대, 2US Air Force Research Lab
키워드 Polyaniline; Carbon nanotube
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