화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.2591
발표분야 분리기술
제목 A new 2-Ethyl-4-Methylimidazole-baced stationary phase for HPLC separation
초록 A new HPLC stationary phase has been synthesized based on the ionic liquid 2-Ethyl-4-methylimidazole chloride. 2-Ethyl-4-methylimidazole was covalently immobi-lized on a silica substrate through an n-alkyl tether, the performance of the resulting stationary phase was determined by Fourier Transform Infrared (FT-IR), Thermogravimetric analysis (TGA), 13C NMR and the retention characteristics of it were evaluated in HPLC by using the mixture of methanol/acetonitrile and water as mobile phase. The retention characteristics of the test solutes show considerable promise for the separation of neutral solutes and points to the potential for a truly multimodal stationary phase.
저자 왕엽, 만효룡, 노경호
소속 인하대
키워드 Ionic liquid; HPLC; stationary phase; retention mechanisms
E-Mail
원문파일 초록 보기