학회 | 한국공업화학회 |
학술대회 | 2007년 가을 (11/02 ~ 11/03, 한경대학교) |
권호 | 11권 2호 |
발표분야 | 정밀화학 |
제목 | A study on the 2-n-butyl-3-fluoropyrrole derivatives |
초록 | A new series of N-substituted 2-n-butyl-3-fluoropyrroles (5) were prepared by a simple one-pot reaction. a,a-Difluoro-g-iodo-g-(trimethylsilyl)propyl n-butyl ketone (3), a precursor molecule for 2-n-butyl-3-fluoropyrroles (5), was prepared from the reaction of vinylsilane (2) with ketone (1) under Cu(0) catalyst. This precursor was reacted with various amines to yield N-substituted 2-n-butyl-3-fluoropyrroles (5) in high yields. |
저자 | 송미선1, 류성렬2, 곽경철1, 채규윤1 |
소속 | 1원광대, 2대불대 |
키워드 | N-substituted 2-n-butyl-3-fluoropyrroles; one-pot reaction |