| 학회 | 한국공업화학회 |
| 학술대회 | 2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 | 19권 1호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Variety pathways of using Alkynyldimethylaluminum Reagents and Aluminum-amide Reagents |
| 초록 | Organoaluminum reagents have proven as remarkable reagents in organic synthesis due to their inherent reactivity, wide range of applicability, low cost and commercial availability. Organoaluminum compounds can easily react with various heteroatoms in organic molecules, particularly with oxygen and nitrogen, even with carbon to form a strong coordinate complex (1:1). As a part of ongoing research on development of new organic synthetic methods, we have utilized alkynyldimethylaluminums for the synthesis of N,N-disubstituted 3-amino-1,4-diynes and 3-amino-1-ynes (Scheme 1), α,β-alkynyl ketones (Scheme 2), N-substituted propiolamides (Scheme 3) and aluminum-amides for N-aryl substituted, five- and six-membered azacycloalkanes, isoindoles and tetrahydroisoquinolines (Scheme 4). |
| 저자 | 정성수, 이상협 |
| 소속 | 대구가톨릭대 |
| 키워드 | Alkynyldimethylaluminum Reagent; Aluminum-amide Reagent |
