| 학회 |
한국공업화학회 |
| 학술대회 |
2010년 봄 (05/13 ~ 05/14, BEXCO(부산)) |
| 권호 |
14권 1호 |
| 발표분야 |
나노 |
| 제목 |
Poly(thiophene) Nanoparticles Prepared by Fe3+-Catalyzed Oxidative Polymerization:A Size-Dependent Effect on Photoluminescence Property |
| 초록 |
Poly(thiophene) (PTh) nanoparticles with various sizes were directly prepared by Fe3+-catalyzed oxidative polymerization of thiophene with varying hydrogen peroxide (H2O2) concentrations. With increasing H2O2 molar concentration from 2.35 to 5.88 M, the average sizes of the PTh nanoparticles decreased from 51 to 12 nm, and their photoemission wavelengths shifted from red to blue color at the maximum excitation wavelength (λUVmax = 400 nm). As a result, we could tune the emitting colors that resulted from variations of the effective conjugation chain length by manipulating the size of PTh nanoparticles. |
| 저자 |
이선종1, 김중현1, 이정민1, 조학제1, 고원건1, 정인우2
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| 소속 |
1연세대, 2경북대 |
| 키워드 |
Polythiophene; Nanoparticles; Color tuning; Oxidative polymerization; Fluorescence spectroscopy
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| E-Mail |
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