화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 콜로이드 및 분자조립 부문위원회 I
제목 In situ polymerization of melanin nanoparticles in hydrogel bilayers for controlled photothermal effect toward programmable actuation
초록 Soft actuators are actively being researched to develop soft robots responding to various stimuli. Although photo-responsive material can adjust deformation by remote control, there has been difficulty in manufacturing to have different driving properties within a single material. We developed a melanin-driven light-responsive hydrogel actuator composed of agar/alginate double-network (DN) hydrogel and N-isopropylacrylamide. For melanin nanoparticles, dopamine precursor was introduced to the pristine hydrogel and in situ oxidation polymerization was proceeded in polymer networks. It was possible to form different melanin concentrations depending on the time and number of polymerization. As hydrogel containing melanin were irradiated, heat was generated by photothermal effect and caused actuation, which leads to shrinkage resulting in shape morphing. Finally, we observed different shape morphing behaviors with different melanin concentration under the same light irradiation condition.
저자 이채원, 심태섭
소속 아주대
키워드 soft actuator; photo-responsive; melanin nanoparticle; in situ polymerization; photothermal effect
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