화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 학생우수논문발표(박사과정)
제목 이산화탄소 개질 반응에서 ZrO2, CeO2, Ce-ZrO2 조촉매 첨가에 따른 Ni-MgO 촉매의 안정성 향상 연구
초록 MgO supported Ni catalysts have been widely applied to carbon dioxide reforming (CDR) reaction due to their coke resistance. However, activation of Ni-MgO catalyst consumes considerable energy because of its very high reduction temperature. In this study, ZrO2, CeO2, and CeO2-ZrO2 promoted Ni-MgO catalysts were prepared via a facile co-precipitation method and applied to the CDR reaction. Among the prepared catalysts, the ZrO2-promoted Ni-MgO catalyst showed the highest reduction degree and CH4 conversion. The high catalytic performance of the ZrO2-promoted Ni-MgO catalyst is mainly due to easier reducibility, high Ni dispersion, and high specific surface area.
저자 김범준, 박호룡, 노현석
소속 연세대
키워드 Carbon Dioxide Reforming of Methane; Ni Dispersion; Reducibility; Reducible Oxide Promoters; Surface Area
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