| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
대학원생 구두발표(영어발표) |
| 제목 |
Synthesis of reactive energetic plasticizers with clickable functionality and their application in energetic polyurethane binders |
| 초록 |
Reactive energetic plasticizers (REPs) containing a terminal alkyne group are synthesized by using the aldol condensation catalyzed with Lewis acid. These REPs are found to work properly as a general plasticizer in GAP-based polyurethane formulation process and then complete the click reaction under Cu-free condition with azide groups of GAP prepolymer in PU curing process. Effect of REP structure on the plasticization to GAP prepolymer and in-situ click reaction during PU process is investigated in detail. Thermal and mechanical properties of REP-integrated GAP-based PUs are also discussed. |
| 저자 |
마명양1, Yechen Shen1, 권영환1, 김진석2, Yan Xu1
|
| 소속 |
1대구대, 2ADD |
| 키워드 |
REP; GAP; “click” reaction; catalyst-free; PU formulation
|
| E-Mail |
|
