| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
| 권호 |
25권 2호 |
| 발표분야 |
[화학물질안전·위해성] 유해 화학물질 안전성과 위험성평가 |
| 제목 |
Degradation studies of nitramine explosives using nano metal oxide PdO |
| 초록 |
The purpose of this study is to solve the environmental pollution problem caused by nitramine explosives such as RDX and HMX at storage facilities or training grounds. The nano PdO catalyst synthesized by the Sol-Gel method was selected to solve this problem. The BET surface area of the PdO used in this experiment was 16.358 m2/g. The degradation experiment was performed at 313 K by mixing an explosive dissolved in water and nano PdO in an NMR tube. A water suppression NMR pulse sequence was used to acquire 1H NMR spectra according to a change in time of a sample containing water. The intensity and chemical shift of peaks on NMR spectrum were used for kinetic analysis. The reaction rate constants of RDX and HMX degradation were 2.10×10-2 and 6.35×10-4 h-1, respectively. This study showed that the application of nano PdO for explosives decomposition is feasible option. |
| 저자 |
계영식, 김동욱
|
| 소속 |
육군사관학교 |
| 키워드 |
Nitramine explosives; Nano metal oxide; NMR
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| E-Mail |
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