화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 석유화학윤활유_포스터
제목 Effect of acidity of zeolite catalysts in esterification of oleic acid dissolved in soybean oil
초록 Effect of acidity of zeolite catalysts was evaluated in esterification of oleic acid dissolved in soybean oil. The catalytic activity of zeolites was studied in the esterification of oleic acid with methanol in soybean oil. The influences of acidity and pore structure of the zeolites were investigated in relation to conversion of the oleic acid on the zeolite catalysts. H+ ion exchanged ZSM-5 (HMFI) and mordenite (HMOR) zeolites conducted with different Si/Al ratio were employed to examine an influence of acidity in the reaction. Conversion of oleic acid was about 80% on HMOR zeolites and HMFI(25) zeolite. The conversion of oleic acid was improved as the amount of acid site increased. The amount of acid site of the zeolites affected significantly the catalytic activity in the esterification of oleic acid.
저자 정상민, 이원준, 정경환, 이헌, 정상철
소속 순천대
키워드 esterification; oleic acid; zeolite; acidity; soybean oil; biodiesel
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