화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 고분자_포스터
제목 Efficient Colorimetric Wide Range Temperature Sensor Based on Fluorescent Block Copolymer Decorated Graphene Oxide
초록 Stimuli-responsive polymers have received a lot of attention as a varied range of application as their properties flexible depending on the environment. Especially, temperature responsive polymer shows drastic change of solubility in given solvent; however, it usually has only one lower critical solution temperature (LCST) and responses to a certain temperature. Herein, we developed a wide range temperature sensor with three kinds of block copolymers (BCPs) composed of temperature responsive part and fluorescent dye part. Through three BCPs-integrated graphene oxide (MP-GO), the distances between GO and fluorescent dye were controlled independently by three linkers which have different LCST. Thus, the MP-GO showed temperature sensing behavior in range of 24 ~ 42 °C, and temperature dependent responses can be easily detected by their distinctive colorimetric changes. In addition, the MP-GO sensor exhibited excellent reversibility and dispersion stability in water, indicating that our system is an ideal platform for environmental and biological applications.
저자 조한희, 박찬호, 양현승, 김범준, 이준혁
소속 KAIST
키워드 FRET; RAFT polymerization; responsive polymer; optical sensor; graphene oxide
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