| 학회 |
한국공업화학회 |
| 학술대회 |
2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터) |
| 권호 |
14권 2호 |
| 발표분야 |
정밀화학 |
| 제목 |
Dimeric Aluminum Complexes with Modified Triethanolateamine Ligands: Synthesis, X-ray structures, Ring Opening Polymerization of Lactide |
| 초록 |
The use of triethanolamine ligand in the chemistry of atrane, which has high stability of the five-membered tricyclic frameworks, has expanded its application across the periodic table. Previous works have shown that alumatranes, which are aluminum complexes with fully deprotonated triethanolamines ligand, have been describe as dimeric in the gas phase; monomeric, hexameric, and octameric in solution; and tetrameric in the solid state. Here we report a selective synthesis of dimeric alumatranes with modified triethanolamines ligands in gas phase, solution, and solid state. Also, we will discuss the ring opening polymerization of lactide using three alumatrane complexes. |
| 저자 |
문정희1, 반희경1, 김소한1, 유태수1, 고영수2, 김영조1
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| 소속 |
1충북대, 2공주대 |
| 키워드 |
aluminum; polymerization
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| E-Mail |
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