| 학회 | 한국화학공학회 |
| 학술대회 | 2009년 가을 (10/22 ~ 10/23, 일산 KINTEX) |
| 권호 | 15권 2호, p.1360 |
| 발표분야 | 공정시스템 |
| 제목 | Modeling of hydrogen peroxide-based epichlorohydrin process |
| 초록 | A liquid-phase epoxidation process using hydrogen peroxide (HP) and titanium silicate (TS-1) is an eco-friendly technology to produce epichlorohydrin. In this work, a mathematical model is built to predict catalyst deactivation, temperature profile, as well as time-varying conversion and selectivity of a packed-bed tubular reactor using HP and TS-1. The reaction mechanism of this process is selected as the Eley-Rideal mechanism and the pertinent kinetic parameters are estimated by genetic algorithms. The optimal operating temperature is identified to maximize catalyst activity in a long-term operation by controlling hot spots of the reactor. In addition, the optimal length of the reactor is also determined to maintain desired conversion and selectivity. Simulation results present both conversion and selectivity could be maintained above 96% during 2,000 hours for the optimally-sized reactor operating at identified optimal conditions. Acknowledgement: This work was supported by Hanwha Chemical R&D Center. |
| 저자 | 김우현1, 윤좌문1, 김 영2, 박정호1, 박선원1, 정기택3, 우경섭3, 이용화3, 김세헌3 |
| 소속 | 1KAIST, 2한국기계(연), 3한화석유화학(주) |
| 키워드 | epichlorohydrin; hydrogen peroxide; TS-1; deactivation; Aspen Custom Modeler |
| VOD | VOD 보기 |
| 원문파일 | 초록 보기 |
