화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 봄 (04/25 ~ 04/26, 순천대학교)
권호 9권 1호, p.427
발표분야 분체공학
제목 분무열분해공정에 의해 제조된 BaMgAl10O17 청색형광체의 발광특성 개선
초록 BaMgAl10O17:Eu2+ (BAM) blue phosphor particles with an improved photoluminescence intensity under the excitation of vacuum ultraviolet(VUV) light were prepared by spray pyrolysis. In order to improve the photoluminescence intensity, Er3+ and Nd3+ ions were used as a co-doping element. The VUV characteristics of BAM:Eu2+,M+(M= Er, Nd) were monitored with varying the Er3+ and Nd3+content in order to find the optimal co-doping concentration when they were prepared by spray pyrolysis. Under the VUV excitation, it was found that doping Er3+ or Nd3+ is greatly helpful to enhance the photoluminescence intensity of BAM:Eu2+ blue phosphor particles. The M3+ doping effect on the photoluminescence intensity was pronounced especially whether were excited at 172 nm. The maximum intensity was obtained when the M3+ content was 1.0 at. % with respect to Ba element. It was also found that the photoluminescence intensity of BAM:Eu2+,M+(M=Er3+, Nd3+) particles was also further improved by making them in spherical shape which was successfully achieved by controlling the spray solution.
저자 이동렬1, 정경열2, 강윤찬2, 박희동2, 유승곤1
소속 1충남대, 2한국화학(연)
키워드 BAM; 청색형광체; 분무열분해공정
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