| 학회 | 한국화학공학회 |
| 학술대회 | 2006년 가을 (10/27 ~ 10/28, 고려대학교) |
| 권호 | 12권 2호, p.1682 |
| 발표분야 | 분리기술 |
| 제목 | Kinetics of Carbon Dioxide in Aqueous Sodium Glycinate Solution |
| 초록 | In the present work, the reaction between CO2 and sodium glycinate has been studied by using wetted wall column apparatus at various temperature. These results would be applied in the basic absorption process related to design of acid gas treatment equipment for acid gas removal in our future work. The physical solubility of N2O and CO2 aqueous sodium glycinate solutions of various concentrations at T = (303.15 to 323.15) K were recorded. It was found that while physical solubility increases with increase in sodium glycinate mass fraction, it decreases with decrease in temperature. The diffusivity of N2O and CO2 in aqueous sodium glycinate solution of various concentrations at different temperatures was also recorded. It was found that diffusivity decreases with increase in sodium glycinate mass fraction and decrease is more severe at higher temperature. Based on the pseudo-first order for the CO2 absorption, the overall pseudo first-order reaction rate constants were determined. The second-order rate constant of CO2 with sodium glycinate was found to be as k2 (m3 kmol-1 s-1) = 1.95×1013 exp[-7670/(T/K)]. |
| 저자 | 이승문1, 송호준1, 산지브 마킨1, 박진원1, 심재구2, 김준한2, 엄희문2 |
| 소속 | 1연세대, 2한국전력(연) |
| 키워드 | Absorption; Kinetics; Physical solubility; Diffusivity; carbon dioxide |
| 원문파일 | 초록 보기 |
