| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_고분자 |
| 제목 |
Synthesis of comb-shaped copolymer based on polysulfone with sulfonated poly triazole side chains for proton exchange membrane |
| 초록 |
Comb-shaped copolymers were synthesized through the azide-alkyne click reaction with polysulfone having azidomethyl side group and sulfonated polytriazole containing a terminal ethynyl group. The different ion exchange capacity values of membranes were obtained by changing the chain length of the sulfonated polytriazole. Since the distinct hydrophilic-hydrophobic phase seperated morphology, the comb-shaped copolymer membrane showed outstanding proton conductivity compared to the sulfonated poly(arylene ether sulfone) membrane having a similar IEC. Furthermore, the mechanical strength of the copolymer was found to be superior to that of the linear polysulfone membrane due to the acid-base interaction between the sulfonic acid and triazole groups in sulfonated polytriazoles. |
| 저자 |
김혜진1, 김기현2, 김정환1, 한주성1, 이현희1, 이종찬1
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| 소속 |
1서울대, 2경상대 |
| 키워드 |
Comb-shaped polymer; sulfonated polytriazole; azide click reaction; acid-base interaction; fuel cell
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| E-Mail |
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