| 학회 |
한국화학공학회 |
| 학술대회 |
2018년 가을 (10/24 ~ 10/26, 대구 EXCO) |
| 권호 |
24권 2호, p.2141 |
| 발표분야 |
[C1가스리파이너리사업단 국제 심포지엄] 화학촉매 관련(촉매부문위원회) |
| 제목 |
Highly stable seed-derived ferrierite for carbonylation of dimethyl ether to methyl acetate: roles of seed content |
| 초록 |
For an efficient syngas conversion to value-added chemicals, the carbonylation of dimethyl ether (DME) to methyl acetate (MA) was investigated using a seed-derived highly crystalline ferrierite zeolite (FER). The seed-derived FER synthesized with different FER-seed content without using any organic structure-directing agent (OSDA) showed a highly active and stable activity for carbonylation of DME to MA at an optimal amount of previously synthesized FER-seed with 15wt%. The FER-seed played an important role to maximize the number of Bronsted acid sites with less coke deposition by concomitant decrease of defect sites through its recrystallization possibly, where the defected Lewis acidic sites on the FER surfaces can be responsible for the preferential coke depositions as well as for the retarded CO insertion rate by preventing the formation of surface acetyl groups. |
| 저자 |
배종욱, 정현승
|
| 소속 |
성균관대 |
| 키워드 |
Carbonylation; Dimethyl ether (DME); Methyl acetate (MA); Seed-derived ferrierite (FER); Structure directing agent (SDA)-free synthesis. |
| E-Mail |
|
| 원문파일 |
초록 보기 |
